Here's a beautiful introduction what Modern Organic Chemistry is, including a historical perspective and a modern approach including pharmaceuticals and neurochemicals. You can downlad it for free here: http://www.oup.com/uk/orc/bin/9780198503460/ch01.pdf
The book: http://www.oup.com/uk/orc/bin/9780198503460/
Chapters on isomerism and Nucleophilic substitution at saturated carbon are also available to download for free in the link above.
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